Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in a segregated and approved area. Store in a dry, cool and well-ventilated area, away from incompatible materials see section Eliminate all ignition sources. Separate from oxidizing materials. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Form: [a]Aerosol Consult local authorities for acceptable exposure limits.
Only components of this product with established exposure limits appear in the box above. Although the levels have been vacated the 11th Circuit Court of Appeals, Baker Hughes recommends that these lower exposure levels be observed as reasonable worker protection.
Recommended monitoring procedures Engineering measures. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Use explosion-proof ventilation equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Take off contaminated clothing and wash before re-use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Butyl rubber gloves. When transferring material wear face-shield in addition to chemical safety goggles.
Not available. Dynamic 25C : cP Soluble Not available. Stability and Reactivity Chemical stability Possibility of hazardous reactions. Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Slightly reactive or incompatible with the following materials: acids. Methanol is incompatible and may react with acetyl bromide, alkyl aluminum solutions, beryllium hydride, boron trichloride, nitric acid, cyanuric chloride, dichloromethane, diethylzinc, metals granulated forms of aluminum and magnesium including aluminum and zinc salts , phosphorus III oxide, and potassium tert-butoxide.
LC50 Inhalation Vapor. Chronic ingestion has shown to cause adverse kidney, liver, bladder, and blood effects in laboratory animals NTP Technical Report, ; Fund. Also, chronic ingestion has caused adverse effect on the sperm decreased motility and increased percentage of abnormal sperm in laboratory animals.
Med, 88, pp ] EG is an animal teratogen at doses which produced mild toxicity to the mother. It was also a teratogen and an embryotoxin at doses producing no toxicity to the mother in laboratory animals. Lamb, J. This makes it unlikely that ethylene glycol itself is the active teratogen in whole animal studies. The EG metabolite, glycolic acid, was active in contrast to EG itself for inducing developmental defects in whole rat embryos in culture Carney et al, EG inhibited metabolic cooperation of Chinese hamster cells in vitro, a finding which may have implications for its mechanism of teratogenicity Loch-Caruso et al, Because methanol is eliminated from the body more slowly than ethanol, it can have cumulative toxicity with repeated exposures ACGIH, Acute dermal, oral, and inhalation exposure to methanol can cause Central Nervous System effects, optic nerve effects, diminished vision, and brain effects necrosis and hemorrhaging.
Bennett, I. Clayton, G. Downie, A et al, , Occupational Medicine, 42, pp Chronic inhalation of methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. Frederick, L. Poon, R et al, , Toxocology and Industrial Health Chronic oral exposure has caused Central Nervous System effects and eye effects in laboratory animals. Pereira, M. Methanol has caused birth defects in rats exposed by the oral Infurna et al, and inhalation Nelson et al, ; Nelson et al, routes.
Embryotoxicity and fetotoxicity were seen with maternal exposure to airborne concentrations of 7, ppm and above, and reduced fetal weights with concentrations of 10, ppm or greater. Toxicological information Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Methanol, gal of this product. Quantity Marine pollutant. Class D-1B: Material causing immediate and serious toxic effects Toxic. Class D-2A: Material causing other toxic effects Very toxic.
Class D-2B: Material causing other toxic effects Toxic. Indicates information that has changed from previously issued version. Baker Hughes, however, makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge.
For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. This MSDS was prepared and is to be used for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Open navigation menu. Close suggestions Search Search. User Settings. Skip carousel.
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Material Safety Data Sheet 1. Hazards identification Potential chronic health effects Chronic effects : Contains material that may cause target organ damage, based on animal data. Target organs : Contains material which may cause damage to the following organs: kidneys, the nervous system, gastrointestinal tract, upper respiratory tract, skin, central nervous system CNS , eye, lens or cornea.
Ingestion : Wash out mouth with water. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Fire-fighting measures Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
Accidental release measures Personal precautions : No action shall be taken involving any personal risk or without suitable training. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Methods for cleaning up Small spill Large spill : Stop leak if without risk. Handling and storage Handling : Put on appropriate personal protective equipment see section 8. Storage : Store in accordance with local regulations. Stability and Reactivity Chemical stability Possibility of hazardous reactions : The product is stable.
Hazardous polymerization Conditions to avoid : Under normal conditions of storage and use, hazardous polymerization will not occur. Materials to avoid : Reactive or incompatible with the following materials: oxidizing materials and reducing materials.
Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Slightly reactive or incompatible with the following materials: acids.
Methanol is incompatible and may react with acetyl bromide, alkyl aluminum solutions, beryllium hydride, boron trichloride, nitric acid, cyanuric chloride, dichloromethane, diethylzinc, metals granulated forms of aluminum and magnesium including aluminum and zinc salts , phosphorus III oxide, and potassium tert-butoxide. LC50 Inhalation Vapor. Chronic ingestion has shown to cause adverse kidney, liver, bladder, and blood effects in laboratory animals NTP Technical Report, ; Fund.
Also, chronic ingestion has caused adverse effect on the sperm decreased motility and increased percentage of abnormal sperm in laboratory animals. Med, 88, pp ] EG is an animal teratogen at doses which produced mild toxicity to the mother. It was also a teratogen and an embryotoxin at doses producing no toxicity to the mother in laboratory animals. Lamb, J.
This makes it unlikely that ethylene glycol itself is the active teratogen in whole animal studies. The EG metabolite, glycolic acid, was active in contrast to EG itself for inducing developmental defects in whole rat embryos in culture Carney et al, EG inhibited metabolic cooperation of Chinese hamster cells in vitro, a finding which may have implications for its mechanism of teratogenicity Loch-Caruso et al, Because methanol is eliminated from the body more slowly than ethanol, it can have cumulative toxicity with repeated exposures ACGIH, Acute dermal, oral, and inhalation exposure to methanol can cause Central Nervous System effects, optic nerve effects, diminished vision, and brain effects necrosis and hemorrhaging.
Bennett, I. Clayton, G. Downie, A et al, , Occupational Medicine, 42, pp Chronic inhalation of methanol can cause Central Nervous System depression, blurred vision, and gastrointestinal effects. Frederick, L. Poon, R et al, , Toxocology and Industrial Health Chronic oral exposure has caused Central Nervous System effects and eye effects in laboratory animals. Pereira, M. Methanol has caused birth defects in rats exposed by the oral Infurna et al, and inhalation Nelson et al, ; Nelson et al, routes.
Embryotoxicity and fetotoxicity were seen with maternal exposure to airborne concentrations of 7, ppm and above, and reduced fetal weights with concentrations of 10, ppm or greater. Toxicological information Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Methanol, gal of this product. Quantity Marine pollutant. Class D-1B: Material causing immediate and serious toxic effects Toxic.
Class D-2A: Material causing other toxic effects Very toxic. Class D-2B: Material causing other toxic effects Toxic. Indicates information that has changed from previously issued version. Baker Hughes, however, makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge.
For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product.
This MSDS was prepared and is to be used for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Open navigation menu. Close suggestions Search Search. User Settings. Skip carousel. Carousel Previous. Carousel Next. What is Scribd? Explore Ebooks.
Bestsellers Editors' Picks All Ebooks. Explore Audiobooks. Bestsellers Editors' Picks All audiobooks. Explore Magazines. Editors' Picks All magazines. Explore Podcasts All podcasts. Difficulty Beginner Intermediate Advanced.
Explore Documents. Defoamer MSDS. Uploaded by fructora. Did you find this document useful? Is this content inappropriate? Report this Document. Flag for inappropriate content. Download now. Related titles. Carousel Previous Carousel Next.
Jump to Page. Search inside document. Material Safety Data Sheet 1. Hazards identification Potential chronic health effects Chronic effects : Contains material that may cause target organ damage, based on animal data. Target organs : Contains material which may cause damage to the following organs: kidneys, the nervous system, gastrointestinal tract, upper respiratory tract, skin, central nervous system CNS , eye, lens or cornea.
Ingestion : Wash out mouth with water. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Fire-fighting measures Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Accidental release measures Personal precautions : No action shall be taken involving any personal risk or without suitable training. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Methods for cleaning up Small spill Large spill : Stop leak if without risk. Handling and storage Handling : Put on appropriate personal protective equipment see section 8. Storage : Store in accordance with local regulations. Stability and Reactivity Chemical stability Possibility of hazardous reactions : The product is stable. Hazardous polymerization Conditions to avoid : Under normal conditions of storage and use, hazardous polymerization will not occur.
Materials to avoid : Reactive or incompatible with the following materials: oxidizing materials and reducing materials. Hazardous decomposition products Conditions of reactivity : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Disposal considerations Waste disposal : The generation of waste should be avoided or minimized wherever possible.
Quantity Marine pollutant Not applicable. CAS number Concentration 10 - 30 10 - 30 : Class B Combustible liquid with a flash point between National Fire Protection Association U. Sampathkumar Attuluri. Palash Kumar Farsoiya.
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